Download (PDF 439 KB): https://research.fs.usda.gov/download/treesearch/39487.pdf
Abstract
Three pulp mills in North America using 50% hydrogen peroxide have suffered explosions of pumps, mixers, and tanks. In two instances, alkali-catalyzed decomposition of peroxide is implicated in the explosion. Although many mechanical pulping facilities use hydrogen peroxide to bleach pulp, no &-catalyzed explosions have been reported. This research uses a kinetic model of peroxide decomposition to explain why the peroxide bleaching process used for mechanical pulps has lower than processes used to bleach chemical pulps.
Keywords
Decomposition,
contamination,
risk management,
explosives,
safety measures,
wood-pulp industry,
bleaching,
pulping,
hydrogen peroxide,
oxidation,
industrial safety,
pulp mills,
catalysis,
chemical reactions,
industrial chemistry,
pulp,
pulp and paper processes,
chemical pulping,
mechanical pulping
Citation
Hart, P.W.; Rudie, A.W. 2010. A comparative evaluation of explosion hazards in chemical and mechanical pulp bleaching systems. Pulp & paper Canada. Vol. 111, no. 4 (July/Aug. 2010): p. 19-22.