Oxidation catalysis by polyoxometalates fundamental electron-transfer phenomena

Yurii V. Geletii; Rajai Atalla; Alan J. Bailey; Laurent Delannoy; Craig L. Hill; Ira A. Weinstock

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Oxidation catalysis by polyoxometalates fundamental electron-transfer phenomena

Informally Refereed

Authors:

Yurii V. Geletii, Rajai Atalla, Alan J. Bailey, Laurent Delannoy, Craig L. Hill, Ira A. Weinstock

Year:

2002

Type:

Miscellaneous Publication

Station:

Forest Products Laboratory

Source:

Proceedings of the 13th International Symposium on Homogenous Catalysis, 2002 September 03-07, Tarragona, Spain. Tarragona, Spain : s.n., 2002: Page 165

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Abstract

Early transition-metal oxygen-anion clusters (polyoxometalates, POMs) are a large and rapidly growing class of versatile and tunable oxidation catalysts. All key molecular properties of these clusters (composition, size, shape, charge density, reduction potential, solubility, etc.) can be systematically altered, and the clusters themselves can serve as tunable ligands for controlling the reactivity of a wide variety of transition-metal cations.

Keywords

Polyoxometalates, oxidation catalysis, electron-transfer phenomena

Citation

Geletii, Yurii V.; Atalla, Rajai H.; Bailey, Alan J.; Delannoy, Laurent; Hill, Craig L.; Weinstock, Ira A. 2002. Oxidation catalysis by polyoxometalates fundamental electron-transfer phenomena. Proceedings of the 13th International Symposium on Homogenous Catalysis, 2002 September 03-07, Tarragona, Spain. Tarragona, Spain : s.n., 2002: Page 165