Treesearch

Selected organosilicon compounds proved effective in stabilizing waterlogged wood dimensions upon drying. However, detailed knowledge about their effect on wood is necessary before introducing them as safe waterlogged wood consolidants in conservation practice. Our previous research showed that organosilicons can chemically react with wood polymers, infiltrate cell walls and/or fill cell lumina. These interactions can mechanically reinforce the cell wall or have a plasticizing effect on wood, depending on the compound applied. To better understand their stabilizing effect on waterlogged...

Membranes are a selective barrier that allows certain species (molecules and ions) to pass through while blocking others. Some rely on size exclusion, where larger molecules get stuck while smaller ones permeate through. Others use differences in charge or polarity to attract and repel specific species. Membranes can purify air and water by allowing only air and water molecules to pass through, while preventing contaminants such as microorganisms and particles, or to separate a target gas or vapor, such as H2 and CO2, from other gases. The higher the flux and selectivity, the better a...

The building industry requires the development of a ductile lateral force–resisting system made of mass timber to allow mass timber to continue to grow in popularity as the primary structural building material. A timber frame with mass ply lam (MPL) beams and columns with a timber buckling-restrained brace (TBRB) was subjected to a quasi-static cyclic loading protocol defined according to the qualification procedure of conventional buckling-restrained braces (BRBs). Two of the TBRBs in this study included a carbon fiber–reinforced polymer (CFRP) wrap to help confine the two ends of the...

Diaphragms transfer the forces exerted by lateral loads to vertical elements through an in-plane shear action. Cross-laminated timber (CLT) has garnered considerable interest as a diaphragm material, particularly for midrise nonresidential construction. This article discusses the findings of tests performed on two full-scale 6.1 m (20 ft) × 6.1 m (20 ft) cantilever CLT diaphragms composed of three-ply CLT panels. The diaphragms were subjected to in-plane shear loads with a cyclic loading protocol. Two different layouts of CLT panels were considered for this study (simple span and two-span...

Gel filtration chromatography (GFC) is a form of aqueous liquid chromatography intended for separation of molecules based on effective molecular volume. With the advent of high-pressure liquid chromatography (HPLC) systems, liquid chromatography techniques have greatly improved. Further improvements have occurred with the development of more rigid and uniform stationary phase resins. GFC applications that employ modern liquid chromatography instrumentation and columns are often dubbed as “high-performance” (HPGFC). Given a need to study the process of enzymatic hemicellulose degradation,...

Rigid lignin foam is prepared by a baking method using kraft lignin as the sole source. The eco-forming process involved cold-pressing kraft lignin powder into a solid block, heating the solid block to form lignin foam, and finally curing and cooling the lignin foam to obtain an open-cell, rigid foam. Both adsorbed water and water generated from the dehydration of hydroxyl groups in the lignin served as the blowing agent in this baking method. It was found that as the moisture content of lignin decreased, the foam densities increased, the mean bubble sizes decreased, and the bubble size...

Thermal conversion of kraft lignin, an abundant renewable aromatic substrate, into advanced carbon materials including graphitic carbon and multilayer/turbostratic graphene has recently attracted great interest. Our innovative catalytic upgrading approach integrated with molecular cracking and welding (MCW) enables mass production of lignin-derived multilayer graphene-based materials. To understand the critical role of metal catalysts in the synthesis of multilayer graphene, this study was focused on investigating the effects of transition metals (i.e., molybdenum (Mo), nickel (Ni), copper...

This study evaluated, for the first time, the feasibility of using 100% microfibrillated cellulose (MFC) for a barrier coating to preserve the shelf life of bananas. MFC was produced from a commercial bleached kraft hardwood pulp through mechanical milling. Barrier coating was accomplished by dipping bananas into aqueous MFC suspensions. Performance of the barrier coating on the banana peel surface was evaluated from visual observations, weight loss, firmness, and dissolved soluble sugars content of the bananas. The results indicated that coating the banana peel surface with MFC delayed...

This study conducted a detailed evaluation of the feasibility of producing cellulose microfibrils (CMF) from a kraft-bleached hardwood pulp at high solid contents with and without pretreatments. CMFs produced by planetary ball milling at solid contents 17 and 28% were compare with those from 1 to 5% under the same milling conditions. Fiber pretreatments using a commercial endoglucanase and mechanical refining using a laboratory PFI mill were also applied before ball milling at a solid content of 28%. Two mechanisms of fiber fibrillation were identified from the results obtained: (i) ball...

Cellulose nanomaterials have been demonstrated to be excellent barriers against grease, oxygen, and other vapors, but their implementation in packaging materials is challenging because of numerous technical and practical challenges. In this work, the oxygen, air, grease, and heptane barrier performance of copy papers coated with cellulose nanocrystals (CNCs), oxidized cellulose nanofibrils (TOCNs), and carboxymethyl cellulose (CMC) weas examined. The effects of different materials and processing conditions were evaluated for their impacts on the resulting barrier properties. TOCN coatings...