Treesearch

Surfactant distributions in model pressure-sensitive adhesive (PSA) films were investigated using atomic force microscopy (AFM) and confocal Raman microscopy (CRM). The PSAs are water-based acrylics synthesized with n-butyl acrylate, vinyl acetate, and methacrylic acid and two commercially available surfactants, disodium (nonylphenoxypolyethoxy)ethyl sulfosuccinate (anionic) and nonylphenoxypoly(ethyleneoxy) ethanol (nonionic). The ratio of these surfactants was varied, while the total surfactant content was held constant. AFM images demonstrate the tendency of anionic surfactant to...

Biomass surrounds us from the smallest alga to the largest redwood tree. Even the largest trees owe their strength to a newly-appreciated class of nanomaterials known as cellulose nanocrystals (CNC). Cellulose, the world’s most abundant natural, renewable, biodegradable polymer, occurs as whisker like microfibrils that are biosynthesized and deposited in plant material in a continuous fashion. Therefore, the basic raw materials for a future of new nanomaterials breakthroughs already abound in the environment and are available to be utilized in an array of future materials once the manufactu...

Perhaps the greatest obstacle facing the acceptance of engineered wood composite products into new markets is the perceived lack of durability. Public perception is that particleboard and other wood-based composites fall apart when exposed to water. This paper will review the unique characteristics of wood based composites that make them more or less susceptible to durability-related problems. Some aspects of chemical and thermal treatments relative to composite durability will also be discussed. Emphasis will be placed on adhesion and interactions with water.

The cellulosic feedstocks (see chapter 2) needed to produce 20 billion gallons per year (BGY) of second-generation and other renewable fuels can come from a wide variety of cropland and forestland sources, including imports. The impact of producing these biofuels on U.S. agriculture and forestry will very much depend on the relative proportions of cropland- and forestland-derived feedstocks and the extent to which imports are used to meet the mandate. To meet the 2022 target, upwards of 240 million dry tons of feedstock would be needed from U.S. croplands if no forest-sourced biomass or...

Obtaining small quantities of custom kiln-dried lumber can be an expensive process for an individual woodworker. Building and operating a small kiln capable of drying custom cuts of lumber (such as slabs, bowl blanks) gives woodworkers another option. Our approach was to build and operate a small dehumidification dry kiln. The four charges of lumber ranged from 600 to 700 board feet (bf), and a woodworker with no dry-kiln experience operated the kiln. The first charge of mixed air-dried 4/4 hardwoods and softwoods was kiln-dried from 18.4% to 7.3% moisture content (MC) in 15 days with no...

In mid-2008, pulp and paper prices were at or near historic peak levels, but global demand conditions were weakening. Industry profits were eroded in 2007 and 2008 as sharply higher energy costs led to higher prices for fuel, freight, pulpwood, recovered paper, chemicals, and other inputs. Expanding pulp and paper capacity in China is having a huge impact on paper and paperboard markets, and on global competition for wood, recovered paper, and pulp. United States net exports of paper and board surged, boosted by the weaker US dollar, while with a strong Canadian dollar net exports and...

ChargeOut!, a discounted cash-flow methodology in spreadsheet format for analyzing machine costs, is compared with traditional machine-rate methodologies. Four machine-rate models are compared and a common data set representative of logging skidders’ costs is used to illustrate the differences between ChargeOut! and the machine-rate methods. The study found that the machine-rate methodologies were not standardized and the methodologies had differences in accounting for ownership, other fixed costs, and variable operating costs. The result was that two of the machine-rate models calculated...

A pilot study to assess the structure, function, and health of Wisconsin’s street trees was initiated in 2002. Almost 900 plots were established in Wisconsin’s urban areas. Table 1 provides an overview of plot-level data, population estimates, and a calculated monetary value for Wisconsin’s street trees. Wisconsin has mid-sized street trees, dominated by Norway maple (30 percent), green ash (15 percent), honey locust (8 percent), and littleleaf linden (7 percent). Field assessments of crown dieback indicated robust and healthy trees in 2002. Damage was observed on only 16 percent of trees,...

Paint companies usually recommend that topcoats be applied to primer paint within two weeks. Unfortunately, this is not always possible. For example, onset of winter weather shortly after applying primer may delay topcoat application until spring. Scuff sanding or repriming are often recommended remedial methods for preparing a weathered primer for topcoats, but there is little research using modern paint formulations to support these practices. Western redcedar boards having a single coat of oil-alkyd or acrylic latex primer were placed outdoors for six months (November 1995 to May 1996)...

Wood specimens were treated with sol-gel systems based on metalorganic precursors of silicon (Si), iron (Fe), zirconium (Zr), and titanium (Ti). The effect of these sol-gel systems on weathering properties of wood was investigated. These sol-gel systems were found to have a positive effect on surface color stability and water vapor resistance of the specimens. Under accelerated weathering conditions, the sol-gel systems retarded the degradation of the wood fiber. Scanning electron microscopy (SEM) and energy dispersive x-ray analysis (EDXA), after accelerated weathering in a Weather-Ometer™...