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An equivalent strain method was used to analyze and determine material relaxation properties for specimens from particleboard, high density fiberboard, and medium density fiberboard. Cantilever beams were clamped and then deflected to 11 m and held for either 2 h or 3 h, while the load to maintain that deflection was measured vs. time. Plots of load relaxation for each specimen showed similar load relaxation vs. time even though there were some slight differences in the maximum load per sample. Three models were developed to fit the relaxation data. The first model was a simple log...

The industrial production of palm oil concurrently generates a substantial amount of empty fruit bunch (EFB) fibers that could be used as a feedstock in a lignocellulose based biorefinery. Lignin byproducts generated by this process may offer opportunities for the isolation of value-added products, such as p-hydroxybenzoate (pBz), to help offset operating costs. Analysis of the EFB lignin by nuclear magnetic resonance (NMR) spectroscopy clearly revealed the presence of bound acetate and pBz, with saponification revealing that 1.1 wt% of the EFB was pBz; with a lignin content of 22.7 %, 4.8...

Soil and plant stable nitrogen isotope ratios (15 N) are influenced by atmospheric nitrogen (N) inputs and processes that regulate organic matter (OM) transformation and N cycling. The resulting 15N patterns may be useful for discerning ecosystem differences in N cycling. We studied two ecosystems; longleaf pine wiregrass (LLP) and Appalachian hardwood (AHW) forests in SE USA under different management regimes. In LLP burning removes OM. In AHW, clearcutting creates large OM pulses of logging residue. Although burning removes OM and clearcutting creates a pulse-addition of OM both managemen...

Two 100Fe/4Cu/4K/6Zn catalysts were prepared using two different methods: coprecipitation or impregnation methods. The effect of the preparation methods on the catalyst structure, catalytic properties, and the conversion of biomass-derived syngas via Fischer–Tropsch synthesis was investigated. Syngas was derived from gasifying Southern pine woodchips and had the composition of 3.1% CH4, 11% CO2, 17%H2, 22%CO, and47%N2. The results show that the coprecipitated Zn-promoted catalyst had higher extent of reduction and carburization, which led to higher carbon conversion and C5+ selectivity of...

The anatomical and chemical characteristics of sweetgum were studied after 11 years of elevated CO2 (544 ppm, ambient at 391 ppm) exposure. Anatomically, branch xylem cells were larger for elevated CO2 trees, and the cell wall thickness was thinner. Chemically, elevated CO2 exposure did not impact the structural components of the stem wood, but non-structural components were significantly affected. Principal component analysis (PCA) was employed to detect differences between the CO2 treatments by considering numerous structural and chemical variables, as well as tree size, and data from...

Protecting wood products from biodeterioration has been a dynamic area of research in the past decade with an emphasis on the development of non-arsenical wood preservatives. Naturally occurring cellulose nanomaterials that are reported to have unique chemical properties, high strength, and stiffness were evaluated for the potential to improve durability of wood either as a stand-alone treatment or in combination with a cationic biocide. In this study, benzalkonium chloride (ADBAC) was selected as a biocidal counter-cation for the sulfate ester on cellulose nanocrystals (CNC). In a...

Lignocellulosic biomass (Moso Bamboo, Chinese tallow tree wood, switchgrass, and pine wood) was subjected to a novel delignification process using microwave energy in a binary glycerol/methanol solvent. The physicochemical properties of the recovered lignin were analyzed prior to its application in the fabrication of polylactic acid (PLA)–lignin composites. The results showed that the samples had a high Klason lignin content (>75%) and retained their natural structure. Thermogravimetric analysis revealed that the recovered lignin exhibited a different thermal decomposition pattern from...

In this article, moso bamboo blocks were first treated with hydrochloric acid solvents with different concentrations or microwave treatments with various microwave output power and treatment durations. The results showed that the crystalliferous region of cellulose of moso bamboo blocks formed porous or swelling type structures under hydrochloric acid pretreatment conditions; the mechanical strength of the moso bamboo decreased when the percentage of hydrochloric acid pretreatment solvents increased from 0 to 3%. When the moso bamboo blocks were treated with microwave, the internal water...

The research reported here quantifies the ecosystem services and values of vacant land using the City of Roanoke, Virginia as a study site. Aerial photo interpretation with ground-truthing was used to identify and catalog vacant parcels of land within the city limits and the results mapped using the i-Tree Canopy and i-Tree Eco models to define land cover classes and quantify ecosystem structure and services. An analysis of urban forest cover in Roanoke’s vacant land reveals that this area has about 210,000 trees, with a tree cover of 30.6%. These trees store about 97,500 t of carbon,...

Paired watershed studies have historically been used to quantify hydrologic effects of land use and management practices by concurrently monitoring two neighboring watersheds (a control and a treatment) during the calibration (pre-treatment) and post-treatment periods. This study characterizes seasonal water table and flow response to rainfall during the calibration period and tests a change detection technique of moving sums of recursive residuals (MOSUM) to select calibration periods for each control-treatment watershed pair when the regression coefficients for daily water table elevation...