Treesearch

Cellulose nanocrystals (CNCs) show promise for enhancing properties of waterborne latexes and coatings. Miniemulsion polymerization is a promising route to obtaining well-controlled latex distributions sufficient to encapsulate CNCs in the monomer phase. Here, we demonstrate the first miniemulsion polymerization resulting in encapsulation of CNCs that incorporates costabilizer, water soluble initiator, and comonomer mixtures, aspects that are important for practical implementation. CNCs were added to the monomer phase as either unmodified (umCNC) or one of two functionalized forms:...

Each year, wildfires ravage the western U.S. and change the lives of millions of inhabitants. Situated in southern California, coastal Santa Barbara has witnessed devastating wildfires in the past decade, with nearly all ignitions started by humans. Therefore, estimating the risk imposed by unplanned ignitions in this fire-prone region will further increase resilience toward wildfires. Currently, a fire-risk map does not exist in this region. The main objective of this study is to provide a spatial analysis of regions at high risk of fast wildfire spread, particularly in the first two...

Forest treatments reduce wildfire risk and can promote the vigor and production of remaining trees, but they are also a disturbance. Understanding the type, timing, and longevity of tree response to treatment, as well as the potential for interactive effects of treatments and drought, could help managers plan and evaluate forest management practices. Environmental drivers, biological modifiers, and tree capacity to respond to prior disturbances were concurrently tested to predict ponderosa pine basal area increment (ΒΑΙ) in a lowland and upland dry pine forest in south central Oregon, USA....

Tree mortality in Sierra Nevada’s 2012–2015 drought was unexpectedly excessive: ~152 million trees died. The relative performance of five drought indices (DIs: SPEI, AI, PDSI, scPDSI, and PHDI) was evaluated in the complex, upland terrain which supports the forest and supplies 60% of Californian water use. We tested the relative performance of DIs parameterized with on-site and modeled (PRISM) meteorology using streamflow (linear correlation), and modeled forest stand NDVI and tree basal area increment (BAI) with current and lagged year DI. For BAI, additional co-variates that could modify...

We used numerical modelling to explore the role of the vertical compartmentalization of hillslopes on groundwater flow and recession discharge. We found that, when hydraulic properties are vertically compartmentalized, streamflow recession behaviour may strongly deviate from what is predicted by groundwater theory that considers the drainage of shallow reservoirs with homogeneous properties. We further identified the hillslope configurations for which the homogeneous theory derived from the Boussinesq solution approximately holds and, conversely, for those for which it does not. By...

Reactive chemical modifications have been shown to impart decay resistance to wood. These modifications change hydroxyl availability, water uptake, surface energy, and the nanostructure of wood. Because fungal action occurs on the micro and nano scale, further investigation into the nanostructure may lead to better strategies to prevent fungal decay. The aim of this article is to introduce our findings using small angle neutron scattering (SANS) to probe the effects of chemical modifications on the nanostructure of wood fibers. Southern pine wood fiber samples were chemically modified to...

Post-fibrillation endoglucanase treatment was employed to reduce the entanglement of cellulose nanofibrils (CNFs) produced with low extent of mechanical milling. The results showed that post-fibrillation endoglucanase treatment can effectively reduce the fibril degree of polymerization (DP) values and therefore entanglement. Cellulose DP was reduced from 520 for CNFs prepared by milling using a SuperMassColloider with 1 pass to 225 after endoglucanase treatment at a low dosage of 1 mg protein/g fibril for 24 h. Endoglucanase treatment can also effectively reduce the fibril mean diameter...

Adverse effects of wildfires can be mitigated within fuel treatments, but empirical evidence of their effectiveness across large areas is needed to guide design and implementation at the landscape level. We conducted a systematic literature review of empirically based studies that tested the influence of landscape-level fuel treatments on subsequent wildfires in North America over the past 30 years to evaluate how treatment type and configuration affect subsequent wildfire behavior or enable more effective wildfire response.

Plant communities are predicted to be more resistant to invasion if they are highly productive, harbor species with similar functional traits to invaders, or support species with high competitive potential. However, the strength of competition may decrease with increasing abiotic stress if species more heavily invest in traits that confer stress tolerance over competitive ability, potentially influencing community trait–resistance relationships. Recent research examining how community traits influence invasion resistance has been predominantly focused on single vegetation types, and...

Losses of C and N from the forest floor and top 20-cm of soil were estimated following separate severe wildfires at two Long-Term Soil Productivity sites in the Sierra Nevada of California, USA. Experimental treatments applied 20 years prior to the wildfires included factorial combinations of 1) organic matter (OM) removal following clear-cut harvesting (SO, stem only harvest, WTH, whole-tree harvest, and WTH + FF, WTH plus the forest floor removal), 2) soil compaction (three levels of intensity), and 3) with and without understory vegetation control. Wildfires caused complete losses of...