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- Standalone cellulose nanofibril (CNF) films have a natural tendency to shrink upon drying from wet conditions due to capillary drying stresses. This shrinkage happens in both the radial direction, and the vertical direction. In this study, we prepared two types of CNF films- one in a restrained condition that did not allow shrinkage in the radial direction but enabled it in the vertical direction and another with 11 % radial shrinkage but limited vertical shrinkage. The radial shrinkage led to a more porous structure than the vertical shrinkage, which brought about poorer oxygen/moisture...AuthorsMd Ikramul Hasan, Jinwu Wang, Mehdi TajvidiKeywordsSourceCarbohydrate PolymersYear2024
- Wild (or lowbush) blueberries (Vaccinium angustifolium Ait.) undergo severe drought impacts due to climate warming because they grow in sandy soils with poor water retention. The feasibility was studied for using biochar in a forest biomass-fueled combined heat and power (CHP) plant to amend the sandy soils. The chemico-physical properties (e.g., bulk density, moisture content, porosity, pH) of the biochar were measured. An acid treatment method (1% to 3% acidic or citric acid solution) was developed to decrease the biochar pH from 11.4 to neutral or lower, aiming to aid in weed control in...AuthorsAbigayl Novak, Ling Li, Jay Wason, Jinwu Wang, Yong-Jiang ZhangSourceBioResourcesYear2024
- Microfibrillated, nanofibrillated, and nanocrystalline cellulose materials are next-generation biobased cellulose materials with applications in the food industry as food contact materials and functional ingredients. Manufacturers have adopted a proactive approach to demonstrate the safety of these cellulose materials as they contribute toward a more sustainable economy. Animal studies and alternative testing approaches are needed to fill data gaps in the literature for the physicochemical and toxicological characterization of cellulose materials. Recently, the European Food Safety...AuthorsYueyang Zhang, Douglas M. Fox, Kimberly J. Ong, James Ede, Christie Sayes, Heli Kangas, Leppänen Ilona, Michael Goergen, Robert J. Moon, Jo Anne. ShatkinKeywordsSourceTrends in Food Science & TechnologyYear2024
- Antibiotics are used for the well-being of human beings and other animals. Detectable levels of antibiotics can be found in pharmaceutical, municipal, and animal effluents. Therefore, the treatment of antibiotic contaminated water is of great concern. In this study, we fabricated a sustainable aminated/TEMPO cellulose nanofiber (Am/TEMPO-CNF) aerogel to remove oxytetracycline (OTC) and chloramphenicol (CAP) from synthetic wastewater. The prepared aerogel was characterized using different analytical techniques such as elemental analysis, FTIR, TGA, SEM-EDS, and N2 adsorption–desorption...AuthorsRabia Amen, Islam Elsayed, Gregory Schueneman, El Barbary. HassanKeywordsSourceGelsYear2024
- A timber lateral force resisting system (LFRS) with timber buckling-restrained braces (TBRB) is proposed to improve the seismic performance of timber buildings. Using a similar design approach for conventional buckling-restrained braced frames (BRBF) and established design methods for timber connections, a timber buckling-restrained braced frame (TBRBF) was designed and tested under a series of quasi-static cyclic loading protocols. During the tests, the level of axial load applied to the column was varied to simulate gravity loads. Additionally, some of the tests included an out-of-plane...AuthorsE. Williamson, C. Pantelides, H.-E Blomgren, Douglas R. RammerKeywordsSourceProceedings of the 18th World Conference on Earthquake EngineeringYear2024
- Surface-functionalized cellulose materials are developed for various purposes, including food additives and food contact materials. A new biologically relevant testing strategy has been developed based on guidance from the European Food Safety Authority to demonstrate the safety of several next-generation surface-functionalized cellulose materials. This strategy involves a complex three-stage simulated digestion to compare the health effects of thirteen novel different types of cellulose. The physical and chemical properties of surface-functionalized fibrillated celluloses differed...AuthorsAmanda K. Charlton-Sevcik, Clancy Collom, James Y. Liu, You-Lo Hsieh, Nicole M. Stark, James D. Ede, Jo Anne Shatkin, Christie M. SayesKeywordsSourceInternational Journal of Biological MacromoleculesYear2024
- Prior work on computer-vision wood identification (CVWID) for North American hardwoods yielded two independent deep learning models a 22-class model for diffuse-porous woods and a 17-class model for ring-porous woods but did not address semi-ring-porous woods nor provide a CVWID solution for an unknown specimen without a human first determining which model to deploy. As untrained human operators would lack the anatomical proficiency to differentiate among porosity domains, it is necessary to develop a consolidated model that can identify diffuse-, ring-, and semi-ring-porous woods....AuthorsFrank C. Owens, Prabu Ravindran, Adriana Costa, Rubin Shmulsky, Alex C. WiedenhoeftKeywordsSourceJournal: BioResourcesYear2024
- Cellulose nanocrystals (CNC) are desirable material due to universal accessibility, and superior mechanical properties. A major challenge is non-uniform dispersion of CNC in the hydrophobic matrices due to their tendency to agglomerate. A novel technique was evaluated to prepare a hybrid system of cellulose nanocrystal (CNC)/graphene quantum dots (GQD). Hybrid system of CNC/GQD was added to high density poly (ethylene) (HDPE) to manufacture composites. The CNC/GQD inclusion complex properties were evaluated using Zeta potential measurement, Raman spectroscopy, X-ray photoelectron spectrosco...AuthorsDilpreet S. Bajwa, Saptaparni Chanda, Cecily Ryan, Sreekala G. Bajwa, Nicole M. Stark, Kirsten MattesonKeywordsSourceJournal: Carbohydrate Polymer Technologies and ApplicationsYear2024
- Amphiphilic sulfated cellulose nanofibrils were synthesized with yields in excess of 99% by sulfation of dissolving pulp cellulose using chlorosulfonic acid in anhydrous N,N-dimethyl formamide followed by high-speed blending. The sulfation level was stoichiometrically tunable to between 1.48 and 2.23 mmol g−1. The optimized SCNF demonstrated the ability to act as an effective dispersant for graphene produced via exfoliation in aqueous media, allowing for the production of aqueous stabilized graphene with 3.9 ± 0.3 wt% graphite to graphene conversion and suspended solids comprised of 19.5 ±...AuthorsBenjamin Pingrey, James D. Ede, Christie M. Sayes, Jo Anne Shatkin, Nicole M. Stark, You-Lo HsiehKeywordsSourceJournal: RSC AdvancesYear2024
- The current trends in climate change have captured the attention of stakeholders across multiple industries, including the building sector. With the introduction of innovative building materials such as mass timber products (MTPs), it has become essential to evaluate their environmental performance. In response, a variety of life cycle assessment (LCA) software programs are available to meet this need. However, it is crucial to understand how different LCA software and databases might influence the results. This study was aimed at exploring the impact of two widely used LCA software...AuthorsChang Gu, Hongmei Gu, Meng Gong, Janet Blackadar, Nadia ZahabiKeywordsSourceJournal: Sustainable StructuresYear2024