Treesearch

Nonspecific (nonproductive) binding (adsorption) of cellulase by lignin has been identified as a key barrier to reduce cellulase loading for economical sugar and biofuel production from lignocellulosic biomass. Sulfite Pretreatment to Overcome Recalcitrance of Lignocelluloses (SPORL) is a relatively new process, but demonstrated robust performance for sugar and biofuel production from woody biomass especially softwoods in terms of yields and energy efficiencies. This study demonstrated the role of lignin sulfonation in enhancing enzymatic saccharification of lignocelluloses – lignosulfonate...

Instrumented indentation is a technique that can be used to measure the elastic properties of soft thin films supported on stiffer substrates, including polymer films, cellulosic sheets, and thin layers of biological materials. When measuring thin film properties using indentation, the effect of the substrate must be considered. Most existing models for determining the properties of thin films from indentation measurements were developed for metal and dielectric films bonded to semiconductor substrates and have been applied to systems with film-substrate modulus ratios between 0.1 and 10....

Lum, Taylor, and Zidek have proposed a revised procedure for wood species grouping in ASTM standard D 1990. We applaud the authors’ recognition of the importance of considering a strength distribution’s variability as well as its fifth percentile. However, we have concerns about their proposed method of incorporating this information into a standard. We detail these concerns in this paper. We also provide both theoretical and empirical arguments that suggest that revisions of the standard should not be based on a two-parameter Weibull assumption.

Enhanced Heat Release Rate (HRR) methodology has been extended to the Mass Loss Calorimeter (MLC) and the Modified Schlyter flame spread test to evaluate fire retardant effectiveness used on wood based materials. Modifications to MLC include installation of thermopile on the chimney walls to correct systematic errors to the sensible HRR calculations to account for radiant energy losses to the chimney walls. Additionally, pure ethylene glycol for low flame radiant losses and the PMMA for high flame radiant losses supplanted the use of methane for calibrating the sensible HRR. The FPL 3 MW...

The recorded history of bonding wood dates back at least 3000 years to the Egyptians (Skeist and Miron 1990, River 1994a), and adhesive bonding goes back to early mankind (Keimel 2003). Although wood and paper bonding are the largest applications for adhesives, some of the fundamental aspects leading to good bonds are not fully understood. Better understanding of these critical aspects of wood adhesion should lead to improved wood products. The chemistry of adhesives has been covered in detail (Pizzi 2003a—f); however, the fundamentals of adhesive mechanical performance are not well...

Since current standard laboratory methods are time-consuming macro-assays that rely on subjective visual ratings of mould growth, rapid and quantitative laboratory methods are needed to screen potential mould inhibitors for use in and on cellulose-based products. A colorimetric micro-assay has been developed that uses XTT tetrazolium salt to enzymatically assess metabolic activity in mould spores, saving significant time and resources (i.e. wood specimens). Minimal inhibitory concentration (MIC90) of isothiazolinone, a known mould inhibitor, in the XTT assay was the same or within a...

For further progress of novel foam core particleboards, their fire performance was examined with cone calorimetry tests (ASTM E 1354-11a). Specimens with varying surface layer thicknesses, foam densities (polystyrene foam), and processing temperatures were tested. Using the initially recommended cone irradiance of 35 kW/m2, different flammability parameters were measured. In comparison to particleboards, the foam core panels generally had much higher heat release rates, somewhat higher heat of combustion and much higher smoke production due to the EPS-foam component of tested panels. The...

SPORL (Sulfite Pretreatment to Overcome Recalcitrance of Lignocellulose) pretreatment was applied to switchgrass and optimized through an experimental design using Response Surface Methodology within the range of temperature (163–197 °C), time (3–37 min), sulfuric acid dosage (0.8–4.2% on switchgrass), and sodium sulfite dosage (0.6–7.4% on switchgrass). Performance of SPORL was compared with that of dilute acid (DA) and alkali (AL) in switchgrass pretreatment. Results indicated that SPORL pretreatment improved the digestibility of switchgrass through sufficiently removing hemicellulose,...

Surface properties of wood play an important role when wood is used or processed into different commodities such as siding, joinery, textiles, paper, sorption media, or wood composites. Thus, for example, the quality and durability of a wood coating are determined by the surface properties of the wood and the coating. The same is true for wood composites where the efficiency of stress transfer from the wood component to the nonwood component is strongly influenced by the surface properties of both components.

Forests, and the wood they produce, have played an important role in human activity since before recorded history. Indeed, one of the first major innovations was utilizing fire, fueled by wood, for cooking and heating. It is very likely that early hominids used wood fires for cooking, as long as 1.5 million years ago (Clark and Harris 1985). Clear evidence of this use of wood exists from sites 400,000 years old (Sauer 1962). Since this ancient beginning, the uses of wood, and the value of the forest, have expanded dramatically, as the populations of humans and their economies grew. Wood...