Treesearch

Wood and plants are made of fibers that contain, in addition to cellulose, lignin and hemicelluloses. Xylan and galactoglucomannan are the dominant secondary cell wall hemicelluloses. In modern times, fibers are important materials for the biorefinery industry and for developing biocomposites. For these and other applications, the structural analysis of fibers is important, and Raman spectroscopy is among the many analytical techniques used. However, given the structural similarity between hemicelluloses and cellulose, many of their Raman contributions overlap, and the extent to which the...

Bark beetle outbreaks result in massive amounts of deadwood which are a significant carbon reservoir that can impact forest ecosystems. Additionally, bark beetle-introduced symbiotic fungi in beetle-generated deadwood can increase termite presence and feeding. This could alter decomposition rates and saproxylic communities of bark beetle-generated deadwood. However, the fate of bark beetle-generated deadwood after tree mortality has received little attention despite the possibility bark beetles could alter decomposition processes and deadwood residence times at landscape scales following...

To explore the carbon sequestration potential of hardwood forests in the eastern United States, the forest vegetation simulator (FVS) and life cycle assessment (LCA) were integrated to analyze the forest carbon dynamics for the four subregions of the eastern United States: northeast (NE), mid-Atlantic (MA), southeast (SE), and north central (NC). This study quantitatively assessed current forest management practices for timber production and their associated life-cycle environmental impacts. The system boundary was selected to be consistent with the A1 module (extraction and upstream...

Morphological characterization of microfibrillated cellulose (MFC) is critically important to process control in production and product specification for trade and product development yet is extremely difficult. This study evaluated several indirect methods for relative comparison of the morphology of lignin-free and lignin-containing ((L)MFCs). The (L)MFCs studied were produced using a commercial grinder through different passes from a dry lap bleached kraft eucalyptus pulp, a virgin mixed (maple and birch) unbleached kraft hardwood pulp, and two virgin-unbleached kraft softwood (loblolly...

Cellulose nanocrystals (CNCs) are considered a prospective packaging material to partially replace petroleum-based plastics attributed to their renewability, sustainability, biodegradability, and desirable attributes including transparency, oxygen, and oil barrier properties. However, neat CNC films are rigid and too brittle to handle or utilize for packaging applications. Hence different additives, including sorbitol, polyvinyl alcohol (PVA), chitin, and κ-carrageenan (CG) were selected to mix with CNCs for packaging film preparation. The influence of additive categories (plasticizer,...

Multilayer films consisting of nanocellulose and nanochitin as oxygen barrier coatings and a conventional petroleum-based moisture barrier plastic as the substrate have been widely studied for food packaging applications. A challenge with enabling recycling of such hybrid multilayer materials is separating the coating from the substrate. In this work, we studied multilayer films consisting of poly(ethylene terephthalate) (PET) as a model substrate with chitin nanowhiskers (ChNWs) and cellulose nanocrystals (CNCs) as bilayer barrier coatings. Dissolution in aqueous media at different pH...

In this study, we perform a comprehensive examination of the ultrasonic dewatering of cellulose nanofibril (CNF) suspensions, with particular emphasis on the role of fines content. The production of CNFs involves mechanical fibrillation which leads to the presence of different percentages of fines (fibrils under 200 μm) in the final product. Although fines have demonstrated mechanical advantages in composite materials, they also increase water retention by the fibrils, leading to increased dewatering time and energy. We selected two distinct CNF samples with 60% and 90% fines, respectively,...

Diaphragms are used to transmit lateral loads to the vertical elements (e.g., shear walls) of the lateral force resisting system of a structure. The extent of deflection in diaphragms can determine what mechanism needs to be considered during design for transfer of forces to the vertical elements. Current design specifications do not provide equations that engineers can use to determine the deflections in cantilever Cross-Laminated Timber (CLT) diaphragms. In this paper, the CLT shear wall equation prescribed by 2021 Special Design Provisions for Wind and Seismic (SDPWS) was adapted to get...

The wood of African mahogany (Khaya spp.) is known for its high quality and similarity to the more expensive Brazilian mahogany (Swietenia macrophylla King). Interest in African mahogany has been increasing because of the reduced availability of native Brazilian mahogany, which has become illegal to harvest. Most African mahogany comes from managed plantations, so the increased consumption of this wood helps to alleviate issues related to illegal harvesting by reducing the trade of Brazilian mahogany. African mahogany has also been gaining popularity in the United States, particularly for...

The use of composite materials has seen many new innovations for a large variety of applications. The area of reinforcement in composites is also rapidly evolving with many new discoveries, including the use of hybrid fibers, sustainable materials, and nanocellulose. In this review, studies on hybrid fiber reinforcement, the use of nanocellulose, the use of nanocellulose in hybrid forms, the use of nanocellulose with other nanomaterials, the applications of these materials, and finally, the challenges and opportunities (including safety issues) of their use are thoroughly discussed. This...