Treesearch

Cotton is a natural fiber containing more than 95% of cellulose. With worldwide cotton consumption continuously increasing, the amount of cotton waste generated is enormous. Most of the cotton waste ends up in landfill or incinerators, resulting in a huge waste of this excellent natural resource. In this project, cotton waste was recycled to produce polypropylene nanocomposites. Instead of using the traditional two-step nanofiber extraction and compounding technique, an integrated process was adopted to combine nanofibrillation and compounding into one step. Results showed that cotton...

Regardless of their applications, polymers are still considered me­chanically weak and functionally insufficient for certain demanding coating and adhesive uses. To address those issues, nanomaterials have been extensively studied as reinforcing fillers, which have been proven to effectively promote the performance of polymer coatings/adhesives. However, conventional nanofillers are expen­sive and non-biodegradable. Meanwhile, cellulose nanomaterials (CNMs), a class of nanomaterials produced from biomass feedstocks, can circumvent the drawbacks of conventional nanofillers. This re­view...

Self-standing cellulose nanofibril (CNF) films are regarded as one of the promising alternatives to current petroleum-based packaging materials mostly due to their ability to form dense self-assembled structures exhibiting high gas barrier properties. Nonetheless, one of the major obstacles to the commercialization of these materials in packaging applications is the high cost of raw materials and production energy. In his study, we created self-standing films of lignin-containing cellulose nanofibrils (LCNFs) derived from a recycled old corrugated cardboard (OCC) pulp that costs less than...

Inherent hydrophilicity and poor water resistance prevent using lignocellulosic materials as green plastic alternatives to fossil fuel-based plastics. Here, we report a facile metal-ion-modification (MIM) route, swelling with aqueous metal ion solutions, and drying to convert conventional hydrophilic paper and wood pulp into biodegradable hydrophobic paper and tableware without the addition of hydrophobic sizing chemicals/materials. Metal ions such as Fe3+ and Zr4+ can coordinate with pulp fibers’ polar groups (i.e., OH, C=O, and COOH) that induce self-assembly of their surface fibrillated...

Brown-rot fungi lack many enzymes associated with complete wood degradation, such as lignin-attacking peroxidases, and have developed alternative mechanisms for rapid wood breakdown. To identify the effects of culture conditions and wood substrates on gene expression, we grew Fibroporia radiculosa in submerged cultures containing Wiley milled wood (5 days) and solid wood wafers (30 days), using aspen, pine, and spruce as a substrate. The comparative analysis revealed that wood species had a limited effect on the transcriptome: <3% of genes were differentially expressed between different...

This work evaluates wheat straw, switchgrass, and hemp hurd as potential alternatives for producing dissolving pulp using sulfur dioxide (SO2)-ethanol-water (SEW) pulping. The SEW process is described in detail for wheat straw, and the best pulping conditions for this feedstock were 130 °C, 4 h, and 10% SO2 concentration, comprised in a sulfur-ethanol-water ratio of 10-45-45. This resulted in a viscose-grade pulp with 93% α-cellulose, 2.0% hemicelluloses, <0.1% lignin, 0.2% ash content, and a viscosity of 4.7 cP. The best pulping conditions for wheat straw were applied to switchgrass and...

Waterlogged wood conservation is a complex and challenging task. Detailed knowledge about the interactions between the applied chemicals and wood is necessary to ensure the effective and safe conservation of wooden artifacts. The present research aims to determine the mechanism of dimensional stabilization of archeological wood by organosilicon compounds using the combination of synchrotron-based X-ray fluorescence microscopy (XFM) and nanoindentation. Archeological oak wood was treated with methyltrimethoxysilane, (3-mercaptopropyl) trimethoxysilane, or 1,3-bis-[(diethylamino)-3-(propoxy)p...

In this study, we investigated the impact on surface topography and micro-mechanical properties of polyvinyl alcohol (PVA) thin films when loaded with hardwood-derived biocarbon particles (BCP). The PVA/BCP composites were prepared with the conventional film casting method, after varying BCP concentrations of 6, 8, 10, 12, and 20 wt% were added to the PVA solution. Atomic force microscopy (AFM) investigations and nanoindentation tests were performed. The average roughness of the thin films increased with the increase in BCP content. The alternation between dark and light patterns observed...

The use of wood in construction requires knowledge of the mechanical properties and the particularities that wood presents in comparison with other materials used for structural purposes such as steel, concrete, brick, or stone. The introduction mentions the environmental advantages that justify the use of wood today. The orthotropy of wood is one of the differentiating characteristics that must be taken into account when studying its behaviour. The determination of the properties of wood is then addressed from a historical perspective and the differentiation is made between the properties...

Disruption of photosynthesis and carbon transport due to damage to the tree crown and stem cambial cells, respectively, can cause tree mortality. It has recently been proposed that fire-induced dysfunction of xylem plays an important role in tree mortality. Here, we simultaneously tested the impact of a lethal fire dose on nonstructural carbohydrates (NSCs) and xylem hydraulics in Pinus ponderosa saplings. Saplings were burned with a known lethal fire dose. Nonstructural carbohydrates were assessed in needles, main stems, roots and whole plants, and xylem hydraulic conductivity was...