Treesearch

Transparency of environmental impacts for building products is of increasing concern. For wood building products, updating life-cycle assessment (LCA) data are critical to ensure that the corresponding environmental product declarations are of the proper recency to maintain this transparency. This study focused on the developing up-to-date life-cycle inventory (LCI) and associated life-cycle impact assessment (LCIA) data for composite I-joist production in the Southeast (SE) and Pacific Northwest (PNW) regions of the United States. Components of the I-joist production system included in...

Cross-laminated timber (CLT) is an emerging product in the North American mass timber market. Intended to compete with pre-cast concrete panels for modular construction, these laminated wall and floor-sized panels have been successfully used in European construction markets for the past 20 years. However, introduction of this material to areas of North America that have high pressure from subterranean termite and decay fungi may prove detrimental to the potential market for this product. This paper describes ongoing work seeking to describe interactions between CLT with both native and...

Wood-based products can be a sustainable and more environmentally friendly alternative to traditional construction materials because of their reduced contribution to air and water pollution. An integral component of these products is often an adhesive. Because wood is hygroscopic, moisture-induced swelling in the cell walls near the wood– adhesive bondlines can lead to durability and performance issues. Unfortunately, researchers working towards improving the moisture durability of forest products are hindered by an incomplete understanding of the nanoscale mechanisms that contribute to...

Understanding and controlling water in wood is critical to both improving forest products moisture durability and developing new sustainable forest products-based technologies. While wood is known to be hygroscopic, there is still a lack of understanding of the nanoscale wood-water interactions necessary for increased moisture-durability and dimensional stability. My PhD thesis focuses on the development and implementation of neutron scattering methods that can provide insight on both the structural and dynamical changes associated with these interactions so that products with improved...

The status of pilot-scale production methods for cellulose nanorods or nanocrystals and the 2,2,6,6-tetramethyl-4-hydroxypiperidine-1-0xyl (TEMPO) grade of cellu— lose nanofibrils are discussed. Both products appear to be poised for scale-up when markets develop, but there are a number of issues that need to be addressed. This chapter outlines concepts for conversion to continuous processes and other issues and concerns that need to be resolved for investments in commercial-scale pro- duction facilities. For large-scale production of cellulose nanocrystals, topic items include site...

Cellulose nanocrystals (CNCs) are renewable and sustainable filler for polymeric nanocomposites. However, their high hydrophilicity limits their use with hydrophobic polymer for composite materials. In this study, freeze-dried CNCs were modified by transesterification with canola oil fatty acid methyl ester to reduce the hydrophilicity. The transesterified CNCs (CNCFE) were compounded with PLA into nanocomposites. CNCFE with long-chain hydrocarbons plays a role as plasticizer. Increasing CNCFE loadings resulted in clear plasticizing effects. Lower Tg and Tm were achieved for CNCFE-based...

Cellulosic nanofibrils (CNFs) were isolated from one of the most widespread freshwater macroalgae, Aegagropila linnaei. The algae were first carboxylated with a recyclable dicarboxylic acid, which facilitated deconstruction into CNFs via microfluidization while preserving the protein component. For comparison, cellulosic fibrils were also isolated by chemical treatment of the algae with sodium chlorite. Compared with the energy demanded for deconstruction of wood fibers, algal biomass required substantially lower levels. Nevertheless, the resultant nanofibrils were more crystalline...

Acetylation of wood imparts moisture durability, decay resistance, and dimensional stability to wood; however, making durable adhesive bonds with acetylated wood can be more difficult than with unmodified wood. The usual explanation is that the acetylated surface has fewer hydroxyl groups, resulting in a harder-to-wet surface and in fewer hydrogen bonds between wood and adhesive. This concept was evaluated using four different adhesives (resorcinol–formaldehyde, emulsion polymer isocyanate, epoxy, and melamine–formaldehyde) with unmodified wood, acetylated wood, and acetylated wood that...

The fungal decay hazard map used by the American Wood Protection Association (AWPA) currently describes regional decay hazards in ground contact for North America and is based on condition assessments of utility poles from the 1970’s. Current work at the USDA Forest Service, Forest Products Laboratory is underway to analyze soil and wood samples from several National Forests in the different AWPA hazard zones and evaluate fungal biodiversity using next-generation sequencing (NGS) of fungal DNA. The results of these analyses will provide fungal biodiversity data to contribute to the...

Processing strategies were developed to manufacture poly(lactic acid) (PLA) blown films without melt strength enhancers (MSEs). The effects of processing temperature on PLA’s melt properties (shear and elongational viscosities), PLA grades, and other processing conditions [ratio of take-up roller to extruder’s rotational screw speeds or processing speed ratio (PSR) and internal air pressures] on film’s blow-up ratio were examined. Experimental results indicate that extrusion-blown amorphous and semicrystalline PLA films can be successfully manufactured without MSEs by controlling melt...